科研团队（课题组）催化合成与功能有机分子

负责人：朱映光，025-84395207，ygzhu@njau.edu.cn

研究方向：有机合成方法学、不对称催化、天然产物全合成、药物及其中间体的合成和工艺研究

团队成员：陈荣顺

团队（负责人）简介：朱映光，男，1980年10月生，教授，博士生导师。2010年获得华东师范大学有机化学博士学位，师从胡文浩教授，博士期间曾在南开大学元素有机化学国家重点实验室周其林院士课题组交流学习。之后前往美国科罗拉多州立大学史一安教授课题组从事四年的博士后研究，自2014年11月起于美国科罗拉多州立大学任职二级研究员，2015年3月作为高层次人才引进至澳门太阳集团官方网站。主要研究领域包括有机合成方法学、不对称催化、天然产物和功能有机分子全合成、药物及其中间体的合成和工艺研究。近年来，已在国际著名期刊上发表SCI论文20多篇，第一作者SCI论文15篇（影响因子大于20的2篇，大于5.0的9篇，第一作者论文总影响因子近130)，其中多篇论文被著名化学评论杂志Synfacts进行正面评述，论文被引用500余次，获授权专利3项，参与撰写专著一本。曾获得教育部自然科学奖二等奖等科研奖励，2016年入选江苏省第五期“333高层次人才培养工程”第三层次中青年学术技术带头人。

主要成员：陈荣顺，澳门太阳集团官方网站讲师。2010年6月毕业于江苏师范大学，获化学教育专业学士学位。2015年6月毕业于南开大学，获得有机化学博士学位，师从贺峥杰教授。目前主要研究方向分为有机合成方法学，金属有机化学，惰性化学键活化反应研究。

近三年承担的重大、重点项目与课题：
1. 国家自然科学基金(21502096)，2016/01-2018/12，主持；
2. 江苏省自然科学基金(BK20150652)，2015/07-2018/06，主持；
3. 中央高校基本科研业务费专项资金项目(KJQN201629)，2016/01-2018/12，主持；
4. 澳门太阳集团官方网站高层次引进人才科研启动经费，2015/03-2020/03，主持。

近几年取得的代表性科研成果：
1.  Yingguang Zhu, Qian Wang, Richard G. Cornwall, Yian Shi*, “Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic Applications”, Chem. Rev. 2014, 114, 8199–8256. (SCI, IF = 45.661)
2. Yingguang Zhu, Richard G. Cornwall, Haifeng Du, Baoguo Zhao, Yian Shi*, “Catalytic Diamination of Olefins via N–N Bond Activation”, Acc. Chem. Res. 2014, 47, 3665–3678. (SCI, IF = 24.348)
3. Yingguang Zhu,# Tao Xiong,# Wenyong Han,# Yian Shi*, “Copper-Catalyzed Oxidative Homo- and Cross-Coupling of Grignard Reagents Using Diaziridinone”, Org. Lett. 2014, 16, 6144–6147. (SCI, IF = 6.324)
4. Yingguang Zhu, Yian Shi*, “Cu(I)-Catalyzed Sequential Diamination and Dehydrogenation of Terminal Olefins: A Facile Approach to Imidazolinones”, Chem. Eur. J. 2014, 20, 13901–13904. (SCI, IF = 5.696)
5. Yingguang Zhu, Changwei Zhai, Yongli Yue, Liping Yang, Wenhao Hu*, “One-pot three-component tandem reaction of diazo compounds with anilines and unsaturated ketoesters: a novel synthesis of 2,3-dihydropyrrole derivatives”, Chem. Commun. 2009, 1362–1364. (SCI, IF = 6.718)
6. Yingguang Zhu, Baoguo Zhao, Yian Shi*, “Highly Efficient Cu(I)-Catalyzed Oxidation of Alcohols to Ketones and Aldehydes with Diaziridinone”, Org. Lett. 2013, 15, 992–995. (SCI, IF = 6.324) (本文被Synform收录‚ Synform 2013, A85–A86)
7. Yingguang Zhu, Yian Shi*, “Facile Cu(I)-Catalyzed Oxidative Coupling of Anilines to Azo Compounds and Hydrazines with Diaziridinone under Mild Conditions”, Org. Lett. 2013, 15, 1942–1945. (SCI, IF = 6.324)
8. Yingguang Zhu, Yian Shi*, “A facile copper(I)-catalyzed homocoupling of terminal alkynes to 1,3-diynes with diaziridinone under mild conditions”, Org. Biomol. Chem. 2013, 11, 7451–7454. (SCI, IF = 3.487)
9. Yingguang Zhu, Changwei Zhai, Liping Yang, Wenhao Hu*, “Highly Regioselective, Three-Component Reactions of Diazoacetates with Anilines and β,γ-Unsaturated α-Keto Esters: 1,2-Addition versus 1,4-Addition”, Eur. J. Org. Chem. 2011, 1113–1124. (SCI, IF = 3.154)
10. Yingguang Zhu, Hongzhu Kan, Liqin Jiang, Wenhao Hu*, “Practical and Scalable Synthesis of Ethyl (R)-Piperidine-3-acetate”, Synth. Commun. 2012, 42, 1137–1145. (SCI, IF = 0.984)
11. Yingguang Zhu, Changwei Zhai, Wenhao Hu*, “Asymmetric Multicomponent Reactions”, Progress in Chemistry 2010, 22, 1380–1396. (SCI, IF = 0.714)
12. Huaiji Zheng, Yingguang Zhu, Yian Shi*, “Palladium(0)-Catalyzed Heck Reaction/C–H Activation/Amination Sequence with Diaziridinone: A Facile Approach to Indolines”, Angew. Chem. Int. Ed. 2014, 53, 11280–11284. (SCI, IF = 11.336)
13.  Xingao Peng, Yingguang Zhu, Thomas A. Ramirez, Baoguo Zhao, Yian Shi*, “New Reactivity of Oxaziridine: Pd(II)-Catalyzed Aromatic C–H Ethoxycarbonylation via C–C Bond Cleavage”, Org. Lett. 2011, 13, 5244–5247. (SCI, IF = 6.324)
14. Thomas A. Ramirez, Qian Wang, Yingguang Zhu, Huaiji Zheng, Xingao Peng, Richard G. Cornwall, Yian Shi*, “Pd(0)-Catalyzed Sequential C–N Bond Formation via Allylic and Aromatic C–H Amination of α-Methylstyrenes with Diaziridinone”, Org. Lett. 2013, 15, 4210–4213. (SCI, IF = 6.324)
15. Jingjing Ji, Xia Zhang, Yingguang Zhu, Yu Qian, Jing Zhou, Liping Yang, Wenhao Hu*, “Diastereoselectivity Switch in Cooperatively Catalyzed Three-Component Reactions of an Aryldiazoacetate, an Alcohol, and a β,γ-Unsaturated α-Keto Ester”, J. Org. Chem. 2011, 76, 5821–5824. (SCI, IF =4.638)
16. Xia Zhang, Jingjing Ji, Yingguang Zhu, Changcheng Jing, Ming Li, Wenhao Hu*, “A highly diastereoselective three-component tandem 1,4-conjugated addition–cyclization reaction to multisubstituted pyrrolidines”, Org. Biomol. Chem. 2012, 10, 2133–2138. (SCI, IF = 3.487)
17. Baoguo Zhao, Xingao Peng, Yingguang Zhu, Thomas A. Ramirez, Richard G. Cornwall, Yian Shi*, “Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways Involving Cu(II) and Cu(III) Species”, J. Am. Chem. Soc. 2011, 133, 20890–20900. (SCI, IF = 11.444)